Heat oven to 375°. Grease or line with paper liners 2 standard muffin tins and set aside.
In a medium mixing bowl, cream together the two sugars, the egg, and the oil. Stir in the buttermilk* and shredded zucchini.
In a separate bowl, stir together the flour, cocoa powder, baking powder, baking soda, and salt until well combined.
Add the flour mixture to the sugar mixture and gently stir just until the dry and wet ingredients are combined. Be careful not to overmix, as that can result in tough muffins. Gently fold in the semisweet chocolate chips.
Divide the batter evenly between the 24 muffin cups (using an oiled ¼ cup measuring cup per muffin is just about perfect). Bake for 18-22 minutes until an inserted toothpick comes out clean or the top of the muffin springs back when lightly pressed.
Let the muffins cool in their tins for about 10 minutes, and then take them out and serve immediately or allow them to finish cooling on a rack.
Double Chocolate Zucchini Muffins can be stored in an airtight container at room temperature for 24 hours, refrigerated for up to three days, or frozen for up to 3 months. If the muffins have been frozen, allow them to thaw at room temperature for a couple of hours before serving, or warm them from frozen in the microwave for about 20 seconds, depending on the wattage of your microwave. Overheated muffins get really tough, so go easy on the reheating time! Enjoy!